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复杂烃类混合物的蒸汽热容
引用本文:方文军 邵爽. 复杂烃类混合物的蒸汽热容[J]. 高校化学工程学报, 1995, 9(3): 215-220
作者姓名:方文军 邵爽
作者单位:浙江大学化学系,浙江教育学院
基金项目:中国石化总公司重点资助
摘    要:设计和建立适合于多元物系的金属结构气体流动量热计,经标准物质标定,测量误差小于0.7%。测定14复杂烃类混合物-石油馏分于不同温度时的蒸汽热容。讨论蒸汽热容与温度及馏分物性间的关系,给出相应关联式。考察了美国API计算方法对国产原油蒸汽热容的适用性。

关 键 词:气体流动 量热计 热容 石油馏分 蒸汽热容

Vapor Heat Capacity of Complicated Hydrocarbon Mixtures
Fang Wenjun,Lin Ruisen,Li Bin,Li Qinqian. Vapor Heat Capacity of Complicated Hydrocarbon Mixtures[J]. Journal of Chemical Engineering of Chinese Universities, 1995, 9(3): 215-220
Authors:Fang Wenjun  Lin Ruisen  Li Bin  Li Qinqian
Abstract:A multicomponent vapoflow calorimeter made of metals was constructed in this laboratory. The apparatus was calibrated by benzene, the standard substance,the error of which was less than 0.7% at the temperature range from 350K to 700K.The vapor heat capacities at various temperatures for 14 petroleum fractions, the typical complicated hydrocarbon mixtures,were measured for the first time. The relationships for the capacity and temperature, the physical properties of fractions were discussed.The corresponding empirical equations were then given.The results estimated by the API method were also compared with the experimental data.
Keywords:Vapor flow calorimeter   Heat capacity   Mixture   Petroleum fraction
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