Anionic polymerization of fluorine-containing vinyl monomers |
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Authors: | Tadashi Marita Tokio Hagłwara Hiroshi Hamana Yukinori Shoji |
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Affiliation: | (1) Department of Environmental Engineering, Saitama Institute of Technology, Okabe-machi, Osato-gun, 369-02 Saitama, Japan |
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Abstract: | Summary The anionic polymerization of pentafluorophenylmethyl methacrylate (PFPMA) were examined with several anionic initiators. The initiators of relatively low activity such as t-C4H9OK, organozinc compounds and Al(C2H5)3 produced poly(PFPMA) in fairly high yields though no polymer was obtained by the initiations of n-C4H9Li and C2H5MgBr within 7 days. The anionic polymerization reactivity of PFPMA was found to be strongly affected by the pentafluorophenyl group though the e-value of PFPMA is similar to those of methyl methacrylate and benzyl methacrylate.Part 7, Polym. J. 19, 958 (1987) |
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