| 草酸葑醇酯的合成及其表征 |
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| 引用本文： | 袁晓敏,赵振东,徐士超,卢言菊,朱守记.草酸葑醇酯的合成及其表征[J].生物质化学工程,2016,50(4):1-5. |
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| 作者姓名： | 袁晓敏 赵振东 徐士超 卢言菊 朱守记 |
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| 作者单位： | 1. 中国林业科学研究院 林产化学工业研究所;生物质化学利用国家工程实验室;国家林业局 林产化学工程重点开放性实验室;江苏省 生物质能源与材料重点实验室, 江苏 南京 210042;
2. 中国林业 科学研究院林业新技术研究所, 北京 100091 |
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| 基金项目： | 农业科学技术成果转化资金项目(2013GB24320604) |
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| 摘 要： | 以α-葑醇和草酰氯为原料合成草酸葑醇酯，考察了反应条件对葑醇酯化反应的影响，确定了葑醇酯化反应的较佳条件：草酰氯与葑醇的物质的量之比为0.6:1.0，反应温度为55℃，反应时间10h，最佳条件下目标产物收率为93.9%，重结晶后纯度可达99.9%。采用GC-MS、IR、1H NMR、13C NMR等对合成的草酸葑醇酯进行了结构表征。
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| 关 键 词： | 葑醇 草酰氯 草酸葑醇酯 表征 |
| 收稿时间： | 2015-12-18 |
Synthesis and Characterization of Fenchyl Oxalate |
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| YUAN Xiao-min;ZHAO Zhen-dong;XU Shi-chao;LU Yan-ju;ZHU Shou-ji.Synthesis and Characterization of Fenchyl Oxalate[J].Biomass Chemical Engineering,2016,50(4):1-5. |
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| Authors: | YUAN Xiao-min;ZHAO Zhen-dong;XU Shi-chao;LU Yan-ju;ZHU Shou-ji |
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| Affiliation: | 1. Institute of Chemical Industry of Forest Products, CAF;National Engineering Lab. for Biomass Chemical Utilization;Key and Open Lab. of Forest Chemical Engineering, SFA;Key Lab. of Biomass Energy and Material, Jiangsu Province, Nanjing 210042, China;
2. Research Institute of Forestry New Technology, CAF, Beijing 100091, China |
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| Abstract: | Fenchyl oxalate was synthesized by the reaction of α-fenchyl alcohol and oxalyl chloride.The influences of reaction conditions on the esterification were studied.The optimum conditions of the esterification were the molar ratio of oxalyl chloride and fenchyl alcohol 0.6:1.0, reaction temperature 55℃ and reaction time 10h.Under these conditions, the yield of fenchyl oxalate was 93.9%.After recrystallization, the purity could be 99.9%.And the structure of fenchyl oxalate was characterized by GC-MS, IR, 1H NMR and 13C NMR. |
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| Keywords: | fenchyl alcohol oxalyl chloride fenchyl oxalate characterization |
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