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新型PS-HQD功能树脂的合成及其对Au3+ 的吸附性能
引用本文:赵石楠,董学畅,吴立生,孙雯.新型PS-HQD功能树脂的合成及其对Au3+ 的吸附性能[J].贵金属,2009,30(3).
作者姓名:赵石楠  董学畅  吴立生  孙雯
作者单位:1. 云南民族大学,化学与生物技术学院,云南,昆明,650031
2. 云南大学,化学与工程技术学院,云南,昆明,650091
摘    要:以聚苯乙烯树脂小白球为原料,经硝化、还原、接枝等反应,合成了含有硫脲功能基的新型PS-HQD螯合树脂,研究了该树脂对Au3+的吸附性能.结果表明,在实验条件下,新树脂在含有Au3+、Cu2+、Zn2+、Fe3+等离子的混合体系中,对Au3+有较高的吸附容量和良好选择性,在一定条件下,能定量地解吸树脂所吸附的Au3+.

关 键 词:温法冶金  聚苯乙烯  PS-HQD功能树脂  吸附性能

Synthesis of Thiourea Chelate Resin and Its Adsorption Property for Au3+
ZHAO Shinan,DONG Xuechang,WU Lisheng,SUN Wen.Synthesis of Thiourea Chelate Resin and Its Adsorption Property for Au3+[J].Precious Metals,2009,30(3).
Authors:ZHAO Shinan  DONG Xuechang  WU Lisheng  SUN Wen
Affiliation:1.School of Chemistry and Biotechnology;Yunnan Nationalities University;Kunming;Yunnan 650031;China;2.College of Chemical Science and Engineering;Yunnan University;Yunnan 650091;China
Abstract:A new thiourea chelating resin was synthesized through the process of nitrification,reduction and grafting reaction on polystyrene microsphere.The adsorption property of the resin for Au3+ was studied.The results show that the resin has excellent adsorption and selectivity for Au3+ in the coexisting,system of Au3+,Cu2+,Zn2+and Fe3+,and Au3+could be desorbed quantitatively.
Keywords:Au3+
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