|
|||||
|
|
Fe-selective fluorescent probe based on rhodamine B and its application in bioimaging |
|
| Authors: | Zhi-Qiang HuAuthor Vitae Yong-Cheng FengAuthor VitaeHe-Qing HuangAuthor Vitae Lei DingAuthor VitaeXiao-Ming WangAuthor Vitae Cun-Sheng LinAuthor VitaeMing LiAuthor Vitae Cui-Ping MaAuthor Vitae |
| Affiliation: | State Key Laboratory Base of Eco-Chemical Engineering, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, PR China |
| Abstract: | A Rhodamine-based fluorescent and colorimetric chemosensor for Fe3+ ion, acetyl rhodamine-hydroxamate (ARH), was designed and synthesized. Upon mixed with Fe3+ in CH3CN-H2O (1:1, v/v), the spirolactam of ARH was opened, which resulted in the dramatic enhancement of both fluorescence and absorbance intensity as well as the color change of the solution. Background metal ions showed small or no interference with the detection of Fe3+. The Job's plot indicated the formation of 1:1 complex between ARH and Fe3+. Confocal laser scanning microscopy experiments showed that ARH could be used to detect Fe3+ in living cells. |
| Keywords: | Fluorescent chemosensor Colorimetric Rhodamine derivative Fe3+ 1:1 complex |
| 本文献已被 ScienceDirect 等数据库收录！ | |