Plasma graft polymerization of acrylamide onto crosslinked HTPB based PU membrane for pervaporation |
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Authors: | Juin-Yih Lai Chien-Wei Tseng Shih-Liang Huang |
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Affiliation: | (1) Chemical Engineering Department, Chung Yuan University, Chung Li, 32023 Taiwan, ROC;(2) National Chin-Yi Institute of Technology, Taichung, 41111 Taiwan, ROC |
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Abstract: | Pervaporation of water-ethanol mixtures through plasma graft polymerization of acrylamide onto crosslinked hydroxyl terminated poly-butadiene (HTPB) based PU membranes, plasma graft polymerization of acrylamide onto crosslinked PU membrane (AAm-p-CPU), were investigated. The grafting was dependent on the discharge power and pretreatment period. The effects of crosslinking, plasma treatment conditions, feed compositions, and feed temperature on the performance of these membranes were studied. The physical properties of crosslinked membrane were better than those of the uncrosslinked membrane. In addition, compared with crosslinked PU membranes (CPU), the plasma modified crosslinked PU membranes effectively improve the pervaporation separation performances. |
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Keywords: | Polyurethane membrane Hydroxyl terminated polybutadiene Crosslinked Pervaporation Plasma |
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