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PVDF中空纤维复合膜的制备及其性能研究
引用本文:马世虎,吕晓龙,李先锋. PVDF中空纤维复合膜的制备及其性能研究[J]. 天津工业大学学报, 2005, 24(3): 5-8
作者姓名:马世虎  吕晓龙  李先锋
作者单位:天津工业大学,中空纤维膜材料与膜过程教育部重点实验室,天津,300160
基金项目:天津市高等学校科技发展基金资助(030409)
摘    要:研究聚偏氟乙烯(PVDF)中空纤维膜复合膜的制备与性能.扫描电镜和红外光谱等试验结果表明:聚乙烯醇(PVA)在PVDF中空纤维膜表面与戊二醛发生缩醛化反应,形成了复合膜;浸泡时间、PVA浓度、反应时间、温度等反应条件对于复合膜的性能有着较为明显的影响,随着反应温度的提高、反应时间的延长.缩醛化反应充分,膜通量下降明显,膜截留率升高.

关 键 词:聚偏氟乙烯 聚乙烯醇 戊二醛 缩醛化 复合膜
文章编号:1671-024X(2005)03-0005-04
修稿时间:2004-06-02

Preparation and properties of PVDF hollow fiber composite membrane
MA Shi-hu,LU Xiao-long,LI Xian-Feng. Preparation and properties of PVDF hollow fiber composite membrane[J]. Journal of Tianjin Polytechnic University, 2005, 24(3): 5-8
Authors:MA Shi-hu  LU Xiao-long  LI Xian-Feng
Abstract:The preparation of PVDF hollow fiber composite membrane and its properties was studied. The results of FTIR and SEM showed that the crosslinking reaction of PVA by glutaradehyde occurred on the surface of PVDF hollow fiber membrane, thus a composite membrane formed, and the properties of PVDF hollow fiber composite membrane was visibly influenced with reaction conditions,such as soakage time, concentration of PVA, reaction time, reaction temperature and so on. With the reaction temperature and reaction time increased, the flux of PVDF hollow fiber membrane was lowered, and the retention rate of membrane was improved.
Keywords:polyvinylidene fluoride (PVDF)  polyvinyl alcohol (PVA)  glutaradehyde  aldehyde acetal  composite membrane
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