| 两种含环己烯结构联苯型聚醚的合成及表征 |
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| 引用本文： | 王漓江,蹇锡高. 两种含环己烯结构联苯型聚醚的合成及表征[J]. 辽东学院学报(自然科学版), 2007, 14(1): 7-9,50 |
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| 作者姓名： | 王漓江 蹇锡高 |
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| 作者单位： | 辽东学院,材料科学与化学工程学院,辽宁,丹东,118001;大连理工大学,化学工程学院,辽宁,大连,116012 |
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| 摘 要： | 合成了新型聚合单体1—甲基—4,5—二(4—氯代苯甲酰基)环己烯,并与对苯二酚和双酚A经亲核取代反应,成功地合成了两种含环己烯结构的联苯型聚醚聚合物。用FT—IR1、H—NMR、DSC、X—射线衍射等方法对聚合物进行了表征,并研究了聚合物的溶解性能。结果表明,这两种聚合物的玻璃化温度分别为140.37℃和153.51℃,并有良好的溶解性。聚合物含有不饱和双键结构,是一种反应性高分子。
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| 关 键 词： | 聚芳醚 环己烯结构 反应性高分子 合成 |
| 文章编号： | 1673-4939（2007）01-0007-03 |
| 修稿时间： | 2007-01-20 |
Synthesis and Characterization of Two Novel Poly (aryl ether) Polymers Containing Cyclohexene |
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| WANG Li-jiang,JIAN Xi-gao. Synthesis and Characterization of Two Novel Poly (aryl ether) Polymers Containing Cyclohexene[J]. Journal of Liaodong University(Natural Sciences), 2007, 14(1): 7-9,50 |
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| Authors: | WANG Li-jiang JIAN Xi-gao |
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| Affiliation: | 1. College of Material Science and Chemical Engineering, Liaodong University, Dandong 118003, China; 2. College of Chemical Engineering, Dalian University of Technology, Dalian 116012, China |
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| Abstract: | Two novel poly(aryl ether) polymers containing cyclohexene were prepared by nuclelophilic displacement reaction with Hydroquinone and Bisphenol A.The polymers were studied by FT-IR,H-NMR,DSC and X-ray diffraction.It has been proved that they were amorphous plastics with high glass transition temperature(140.37 ℃ and 153.51 ℃ respectively).They were soluble in some solvents at room temperature.They were also intermediate products of cross-linked copolymer and grafted copolymer. |
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| Keywords: | poly(aryl ether) cyclohexene heterocyclic polymer synthesis |
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