Preparation of syndiotactic polyolefins by using metallocene catalysts |
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Authors: | T Asanuma Y Nishimori M Ito N Uchikawa T Shiomura |
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Affiliation: | (1) Osaka Research Laboratory, Mitsui Toatsu Chemicals, Inc, Takaishi, Osaka, Japan |
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Abstract: | Summary Polyolefins having syndiotactic structure were obtained by using 1-methyl-1-ethylidene-(cyclopentadienyl-1′-fluorenyl) zirconium
dichloride and methylaluminoxane as a catalyst. 1-Butene and 4-methyl-1-pentene gave crystalline polymers having syndiotactic
structure, while 1-pentene, 1-hexene and 1-octene gave noncrystalline polymers having syndiotactic structure.
The identification of syndiotactic and isotactic polyolefins was made by 13C-NMR, X-ray diffraction, and differential scanning calorimetry. |
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