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Large-scale synthesis and growth mechanism of boron nitride nanocomposite assembled by nanosheets and nanotubes
Authors:Heng Wang  Man Xu  Hang Ping  Zhengyi Fu
Affiliation:1. Engineering Research Center of Environmental Materials and Membrane Technology of Hubei Province, School of Materials Science and Engineering, Wuhan Institute of Technology, Wuhan, PR China;2. State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan, PR China
Abstract:Boron nitride nanocomposites assembled by nanosheets and nanotubes can exert multi-dimensional synergistic toughening and strengthening effects. This material is expected to be a high-efficiency reinforcement additive in advanced structural ceramics. In this study, we designed a universal method for synthesizing gram-scale boron nitride nanocomposites by annealing the precursor containing catalyst in chemical vapor deposition equipment under flowing ammonia, and a combined growth mechanism of surface-diffusion and solid-liquid-solid is proposed. The boron nitride nanosheets were initially formed by a surface-diffusion reaction between boron trioxide and ammonia at 1300°C. At elevated temperatures (1400°C-1500°C), the boron nitride nanotubes grew in-situ from the nanosheets in the presence of catalysts through a solid-liquid-solid mechanism, forming the desired boron nitride nanocomposite.
Keywords:boron nitride nanosheets (BNNSs)  boron nitride nanotubes (BNNTs)  growth mechanism  multi-dimensional nanocomposite
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