Electrochemical preparation of poly(2,5-dimethoxy-1,4-phenylene) |
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Authors: | Kimihisa Yamamoto Hiroyuki Nishlde Eishun Tsuchida |
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Affiliation: | (1) Department of Polymer Chemistry, Waseda University, 160 Tokyo, Japan |
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Abstract: | Summary p-Dimethoxybenzene was electro-oxidatively polymerized to give poly(2,5-dimethoxy-1,4-phenylene) with high yield. 1,4-Structure of polyphenylene was confirmed by 13C-NMR and IR spectrum. The polymer was deposited on electrode, and electrolysis solvent affected the polymer yield and morphology of the polymer. In a strongly basic solvent the polymerization was inhibited, which suggests that cation radical of p-dimethoxybenzene is an active species of this polymerization. |
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