Thermodynamic Assessments of the Ag-Ni Binary and Ag-Cu-Ni Ternary Systems |
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Authors: | Xing Jun Liu Feng Gao Cui Ping Wang Kiyohito Ishida |
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Affiliation: | (1) Department of Materials Science and Engineering, College of Materials, Xiamen University, Xiamen, 361005, P.R. China;(2) Research Center of Materials Design and Applications, Xiamen University, Xiamen, 361005, P.R. China;(3) Department of Materials Science, Graduate School of Engineering, Tohoku University, Sendai 980-8579, Japan |
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Abstract: | The phase diagram of the Ag-Ni binary system has been evaluated by using the calculation of phase diagrams (CALPHAD) method
based on experimental data of the phase equilibria and thermodynamic properties. Gibbs free energies of the liquid and fcc
phases were described by the subregular solution model with the Redlich–Kister equation. On the basis of the thermodynamic
parameters of the Ag-Ni, Ag-Cu, and Cu-Ni systems, and experimental information of the phase equilibria in the Ag-Cu-Ni system,
the thermodynamic assessment in the Ag-Cu-Ni system was carried out. The calculated results in both the Ag-Ni and Ag-Cu-Ni
systems are in reasonable agreement with experimental data. |
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Keywords: | Ag-Ni system Ag-Cu-Ni system thermodynamic assessment CALPHAD method |
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