| 新型杂化材料[(CH_2)_5NH_2]_3[PMo_(12)O_(40)]·3[(CH_2)_5NH]水热合成与晶体结构 |
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| 引用本文： | 周端文.新型杂化材料[(CH_2)_5NH_2]_3[PMo_(12)O_(40)]·3[(CH_2)_5NH]水热合成与晶体结构[J].吉林化工学院学报,2006,23(3):1-3. |
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| 作者姓名： | 周端文 |
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| 作者单位： | 吉林化工学院,制药与应用化学系,吉林,吉林,132073 |
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| 摘 要： | 采用水热合成方法制备了有机．无机杂化材料(CH2)5NH2]3PMo12O40],晶体结构解析表明,该晶体属正交晶系,Pnma空间群．结晶学参数α=2．4486(2)nm,b=2．1202(3)nm,c=1．193 1(4)nm,β=90．00(0)°,V=6．194 2(9)nm3,Z=4,R=0．061 1,Rw=0．157 3．化合物分子由1个Keggin结构的杂多阴离子PMo12O403-,4个质子化的哌啶构成,十二钼磷酸阴离子和质子化的哌啶分子通过静电引力和氢键相互作用．
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| 关 键 词： | 有机-无机杂化 哌啶 水热合成 Keggin 晶体结构 |
| 文章编号： | 1007-2853(2006)03-0001-03 |
| 修稿时间： | 2006年6月7日 |
Hydrothermal structures of a new organic-inorganic hybrid material [(CH2)5NH2]3[PMo12O40]·3[(CH2)5NH] |
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| ZHOU Duan-wen.Hydrothermal structures of a new organic-inorganic hybrid material [(CH2)5NH2]3[PMo12O40]·3[(CH2)5NH][J].Journal of Jilin Institute of Chemical Technology,2006,23(3):1-3. |
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| Authors: | ZHOU Duan-wen |
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| Abstract: | An organic-inorganic hybrid material (CH2)5NH2]3PMo12O40] was synthesized by hydrother-mal synthesis methods determination for the first time. The crystal structure indicates that crystallizes is in Orthorhombic system, space group Pnma, withα=2.448 6(2) nm, b= 2.120 2(3) nm,c=1.193 1(4) nm,β=90.00(°), V=6.194 2(9) nm3,Z = 4, R =0.061 1,RW=0.157 3. The compound molecule make up of four piperidines act as the counter cations which combines to the PMo12O40]3- anion by static electric force and hydrogen bonding. |
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| Keywords: | organic-inorganic hybrid piperidine hydrothermal synthesis Keggin crystal structure |
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