| 竹炭磺酸催化一步法合成表面活性剂烷基糖苷的研究 |
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| 引用本文： | 柳群英,周文富. 竹炭磺酸催化一步法合成表面活性剂烷基糖苷的研究[J]. 广东化工, 2010, 37(2): 190-193 |
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| 作者姓名： | 柳群英 周文富 |
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| 作者单位： | 三明学院,化学与生物工程系,福建,三明,365004 |
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| 基金项目： | 福建三明学院林产化学海西平台创新项目资助(HX20080) |
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| 摘 要： | 以竹炭磺酸催化一步合成表面活性剂烷基糖苷,采用一步醚化、一锅煮法合成。较佳的工艺条件为,压强约为15 Kpa,n(糖):n(醇)=1:5,w(竹炭磺酸)=0.8%,反应温度115～125℃,反应时间5.0 h,产率为75.11%。结果表明,竹炭磺酸催化效果较好,合成工艺简便易行。
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| 关 键 词： | 绿色催化 烷基糖苷 一步合成 表面张力 结构表征 |
On the Synthesis of Alkyl Polyglucoside by One-Stepwith Charcoal Sulfoacid Catalyst |
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| Liu Qunying,Zhou Wenfu. On the Synthesis of Alkyl Polyglucoside by One-Stepwith Charcoal Sulfoacid Catalyst[J]. Guangdong Chemical Industry, 2010, 37(2): 190-193 |
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| Authors: | Liu Qunying Zhou Wenfu |
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| Affiliation: | Departmenent of Chemical and Bio-Engineering;SanMing College;FuJian 365004;China |
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| Abstract: | The alkyl polyglucoside was synthesized by the direct reaction of glucose and laurel alcohol with charcoal sulfoacid as catalyst. The experiment synthesis the alkyl polyglucoside using sulfoacid as a catalyst by one-step etherification, one-pot Boiling. Qrthogooal experiment indicated a more appropriate operation conditions： pressure of about 15 KPa, n （sugar）： n （alcohol） is 1：5, w （catalyst） = 0.8 %, reaction temperature 115-125 ℃, reaction time 5.0 h synthesis APG.the yield is 75.11%. The optimum process of synthesizing with charcoal sulfoacid as catalyst is stable and easy. |
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| Keywords: | greencatalysis alkyl polyglucosid One-step synthesis Surface tension Charactized-structure |
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