Abstract: | The high-dense nanocrystalline BaTiO3(BT)ceramics with grain size smaller than 100nm have been successfully prepared by the two step sintering and the spark plasma sintering(SPS)process.The successive transitions in nanograin BT ceramics from rhombohedral to orthorhombic,tetragonal and cubic transitions,similar to those in coarse BT ceramics,were revealed by in-situ temperature dependent Raman spectrum.The multiphase coexistence and the diffused phase transition character were demonstrated in the 8nm nanocr... |