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An All-solid-state Cd-selective electrode with a low detection limit
Authors:Shunyang YuAuthor VitaeFuhai LiAuthor Vitae  Wei QinAuthor Vitae
Affiliation:a CAS and Shandong Provincial Key Laboratory of Coastal Environmental Processes, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Yantai 264003, PR China
b Chemistry and Biology College, Yantai University, Yantai 264005, PR China
Abstract:A new all-solid-state Cd2+-selective electrode with a low detection limit was prepared by using conjugated thiophene oligomer α-sexithiophene (α-6T) as solid contact deposited between an ionophore-doped poly(vinyl chloride) membrane and a gold disc substrate. The electrode exhibited a Nernstian response for Cd2+ ions over a wide concentration range of 10−3-10−7 M with a detection limit as low as 1.3 × 10−8 M. Results showed that the fabricated potentiometric sensor was suitable for use within the pH range of 2.0-9.0 and exhibited good reproducibility for long-term measurements.
Keywords:Cadmium   All-solid-state   Ion-selective electrodes   Low detection limit
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