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SGEB气相法干气制乙苯技术的工业应用
引用本文:杨玉祥,邓杨清.SGEB气相法干气制乙苯技术的工业应用[J].石油炼制与化工,2021,52(11):38-41.
作者姓名:杨玉祥  邓杨清
作者单位:中海油东方石化有限责任公司
摘    要:中海油东方石化有限责任公司采用气相法干气制乙苯(SGEB)技术,新建一套120 kt/a乙苯装置,该技术采用烷基化及烷基转移催化剂、五段层式绝热固定床烷基化反应器、催化裂解干气脱丙烯系统、丙苯塔和脱非芳塔等,使得工艺流程简化,投资省,能耗低。装置以催化裂解干气和外购苯为原料,产品乙苯纯度(w)为99.84%,二甲苯质量分数为0.06%,乙烯转化率为98.94%,二乙苯转化率为74.70%,具有较好的经济效益。

关 键 词:  乙烯  乙苯  催化裂解干气  气相烷基化  烷基转移  催化剂  
收稿时间:2021-02-02
修稿时间:2021-07-29

INDUSTRIAL APPLICATION OF GAS-PHASE ALKYLATION TECHNOLOGY SGEB FOR DRY GAS TO ETHYLBENZENE
Abstract:The gas-phase dry gas to ethylbenzene technology (SGEB) was adopted in a new 120 kt/a ethylbenzene unit in CNOOC Dongfang Petrochemical Co.,Ltd. The technology contains alkylation and transalkylation catalysts, five-stage adiabatic fixed-bed alkylation reactor, the FCC dry gas depropylene system, the installation of the propylbenzene column and the non-aromatic column etc., having the advantages of simplified process flow, investment-saving and low energy consumption. The unit uses FCC dry gas and purchased benzene as raw materials. The purity of ethylbenzene is 99.84%, the content of xylene is 0.06%, the conversion rate of ethylene is 98.94%, the conversion rate of diethylbenzene is 74.7%,and the economic benefit is very good.
Keywords:benzene  ethylene  ethylbenzene  FCC dry gas  gas-phase alkylation  transalkylation  catalyst  
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