SGEB气相法干气制乙苯技术的工业应用 |
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引用本文: | 杨玉祥,邓杨清.SGEB气相法干气制乙苯技术的工业应用[J].石油炼制与化工,2021,52(11):38-41. |
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作者姓名: | 杨玉祥 邓杨清 |
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作者单位: | 中海油东方石化有限责任公司 |
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摘 要: | 中海油东方石化有限责任公司采用气相法干气制乙苯(SGEB)技术,新建一套120 kt/a乙苯装置,该技术采用烷基化及烷基转移催化剂、五段层式绝热固定床烷基化反应器、催化裂解干气脱丙烯系统、丙苯塔和脱非芳塔等,使得工艺流程简化,投资省,能耗低。装置以催化裂解干气和外购苯为原料,产品乙苯纯度(w)为99.84%,二甲苯质量分数为0.06%,乙烯转化率为98.94%,二乙苯转化率为74.70%,具有较好的经济效益。
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关 键 词: | 苯 乙烯 乙苯 催化裂解干气 气相烷基化 烷基转移 催化剂 |
收稿时间: | 2021-02-02 |
修稿时间: | 2021-07-29 |
INDUSTRIAL APPLICATION OF GAS-PHASE ALKYLATION TECHNOLOGY SGEB FOR DRY GAS TO ETHYLBENZENE |
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Abstract: | The gas-phase dry gas to ethylbenzene technology (SGEB) was adopted in a new 120 kt/a ethylbenzene unit in CNOOC Dongfang Petrochemical Co.,Ltd. The technology contains alkylation and transalkylation catalysts, five-stage adiabatic fixed-bed alkylation reactor, the FCC dry gas depropylene system, the installation of the propylbenzene column and the non-aromatic column etc., having the advantages of simplified process flow, investment-saving and low energy consumption. The unit uses FCC dry gas and purchased benzene as raw materials. The purity of ethylbenzene is 99.84%, the content of xylene is 0.06%, the conversion rate of ethylene is 98.94%, the conversion rate of diethylbenzene is 74.7%,and the economic benefit is very good. |
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Keywords: | benzene ethylene ethylbenzene FCC dry gas gas-phase alkylation transalkylation catalyst |
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