Etude thermochimique de la synthese en phase vapeur de Y3Fe5O12 |
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| Authors: | NT Linh M Moulin C Fonrouge |
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| Affiliation: | Thomson. CSF Laboratoire Central de Recherches Corbeville 91401 Orsay - France |
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| Abstract: | Thermochemistry of oxidation and hydrolysis of YCl3 and FeCl2 have been studied. It has been shown that Y3Fe5O12 cannot be formed by hydrolysis. Conditions of synthesis have been established in oxidation, particularly it is pointed out that excess of HCl or Cl2 is not recommended for moderating reactions. It makes the synthesis difficult to control. Theoretical results are compared to experimental data. |
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