Effects of poor solvents on radical-radical termination of polymerization |
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Authors: | G.G. Cameron J. Cameron |
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Affiliation: | Department of Chemistry, University of Aberdeen, Aberdeen AB9 2UE, UK |
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Abstract: | It is shown that in poor solvents for the polymer the rate coefficient for radical-radical termination in the polymerization of styrene and methyl methacrylate is diminished compared with that in bulk monomer. It is suggested that this effect is due to the formation of tightly coiled macroradicals which hinder the radical-radical reaction process. |
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