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Simultaneous Reduction and Surface Functionalization of Graphene Oxide by Mussel‐Inspired Chemistry
Authors:Sung Min Kang  Sungjin Park  Daewon Kim  Sung Young Park  Rodney S Ruoff  Haeshin Lee
Affiliation:1. Department of Chemistry and Graduate School of Nanoscience & Technology (WCU), KAIST Institute of NanoCentury. KAIST, Daejeon 305–701, Korea;2. Department of Chemistry, Inha University, Incheon 402–751, Korea;3. Department of Chemical and Biological Engineering, Chungju National University, Korea;4. Department of Mechanical Engineering and the Texas Materials Institute, the University of Texas at Austin, One University Station C2200, 78712, USA
Abstract:This study presents a method of simultaneous reduction and surface functionalization of graphene oxide by a one‐step poly(norepinephrine) functionalization. The pH‐induced aqueous functionalization of graphene oxide by poly(norepinephrine), a catecholamine polymer inspired by the robust adhesion of marine mussels, chemically reduced and functionalized graphene oxide. Moreover, the polymerized norepinephrine (pNor) layer provided multifunctionality on the reduced graphene oxide that includes surface‐initiated polymerization and spontaneous metallic nanoparticle formation. This facile surface modification strategy can be a useful platform for graphene‐based nano‐composites.
Keywords:Graphene oxide  reduction  surface functionalization  polymers  nanoparticles
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