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低温固相法制备二氧化锰/活性炭复合材料
引用本文:张勇,李光胤,王力臻,张爱勤.低温固相法制备二氧化锰/活性炭复合材料[J].电池,2012,42(1):4-6.
作者姓名:张勇  李光胤  王力臻  张爱勤
作者单位:1. 郑州轻工业学院材料与化学工程学院,河南郑州450002;河南省表界面科学重点实验室,河南郑州450002
2. 郑州轻工业学院材料与化学工程学院,河南郑州,450002
基金项目:国家自然科学基金,河南省高校科技创新人才支持计划资助项目,河南省科技厅基础与前沿技术研究项目,河南省高等学校青年骨干教师资助计划项目,郑州市科技攻关项目
摘    要:采用低温固相法制备了超级电容器用二氧化锰(MnO2)/活性炭(AC)复合材料,用XRD、SEM、循环伏安(CV)和恒流充放电测试研究了掺杂量对产物性能的影响。产物的粒径为1~10μm。AC的最佳掺杂量为7%,在0~0.8 V充放电,该样品的100 mA/g首次放电比电容为375 F/g,第100次和1 000次300 mA/g循环的放电比电容分别为99 F/g和74 F/g。

关 键 词:二氧化锰(MnO2)  活性炭  低温固相法  超级电容器

Synthesis of manganese dioxide/activated carbon composite by low temperature solid-state method
ZHANG Yong , LI Guang-yin , WANG Li-zhen , ZHANG Ai-qin.Synthesis of manganese dioxide/activated carbon composite by low temperature solid-state method[J].Battery Bimonthly,2012,42(1):4-6.
Authors:ZHANG Yong  LI Guang-yin  WANG Li-zhen  ZHANG Ai-qin
Affiliation:1,2(1.Department of Material and Chemical Engineering,Zhengzhou University of Light Industry,Zhengzhou,Henan450002,China;2.Henan Provincial Key Laboratory of Surface-interface Science,Zhengzhou,Henan 450002,China)
Abstract:Manganese dioxide(MnO2)/activated carbon(AC) composite for supercapacitor was synthesized by low temperature solid-state method.Effects of doping amount on the performance of the products were studied by XRD,SEM,cyclic voltammetry(CV) and galvanostatic charge-discharge tests.The diameter of the product was 1~10 μm.The optimum doping amount of AC was 7%.When charged-discharged at 0~0.8 V,the initial 100 mA/g specific discharge capacitance of the product was 375 F/g,the specific discharge capacitance in the 100 th cycle and 1 000 th cycle with 300 mA/g was 99 F/g and 74 F/g,respectively.
Keywords:manganese dioxide(MnO2)  activated carbon(AC)  low temperature solid-state method  supercapacitor
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