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溶胶凝胶法制备Ru-Ir-Sn-Ti阳极涂层及其电化学性能研究
引用本文:梁成浩,贾理男,黄乃宝.溶胶凝胶法制备Ru-Ir-Sn-Ti阳极涂层及其电化学性能研究[J].表面技术,2012,41(3):26-29.
作者姓名:梁成浩  贾理男  黄乃宝
作者单位:大连海事大学交通运输装备与海洋工程学院,大连,116026;大连海事大学交通运输装备与海洋工程学院,大连,116026;大连海事大学交通运输装备与海洋工程学院,大连,116026
基金项目:国家高技术研究发展计划资助项目
摘    要:采用溶胶凝胶法制备Ru-Ir-Sn-Ti阳极涂层,对涂层进行析氯电位、析氧电位、极化曲线、循环伏安曲线、电化学交流阻抗等电化学测试以及强化电解寿命测试,并与热分解法制备的阳极涂层进行对比。结果表明:与热分解法制备的阳极涂层相比,溶胶凝胶法制备的Ru-Ir-Sn-Ti阳极涂层具有较低的析氯电位、较高的析氧电位、良好的电催化活性和较长的强化电解寿命。

关 键 词:溶胶凝胶法  析氯电位  电催化活性  强化电解寿命
收稿时间:2012/1/15 0:00:00
修稿时间:2012/6/20 0:00:00

Preparation of Ru-Ir-Sn-Ti Metal Oxide Anode Coating by Sol-gel Method and Study on It's Electrochemical Properties
LIANG Cheng-hao,JIA Li-nan and HUANG Nai-bao.Preparation of Ru-Ir-Sn-Ti Metal Oxide Anode Coating by Sol-gel Method and Study on It''s Electrochemical Properties[J].Surface Technology,2012,41(3):26-29.
Authors:LIANG Cheng-hao  JIA Li-nan and HUANG Nai-bao
Affiliation:(Transportation Equipments and Ocean Engineering College,Dalian Maritime University,Dalian 116026,China)
Abstract:Ru-Ir-Sn-Ti oxideanode coating were prepared by sol-gel method, and the electrochemical property and durability of the anode coating were investigated by oxygen evolution potential, chlorine evolution potential, cyclic voltammetry curve, polarization curve, electrochemical impedance and accelerated lifetime and compared with oxide anode coating prepared by thermal decomposition method. The results show that anode coating prepared by sol-gel method have lower chlorine evolution potential, higher oxygen evolution potential, longer accelerated lifetime and better electro-catalytic activity than metal oxide anodes coating prepared by thermal decomposition method.
Keywords:sol-gel method  chlorine evolution potential  electrocatalytic activity  accelerated lifetime
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