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蓝色发光材料MGa_2S_4:Ce(M=Ca,Sr)发光特性的研究
引用本文:王林军,陈忠传,赵伟明,唐春玖,蒋雪茵,张志林,许少鸿. 蓝色发光材料MGa_2S_4:Ce(M=Ca,Sr)发光特性的研究[J]. 无机材料学报, 1997, 0(3)
作者姓名:王林军  陈忠传  赵伟明  唐春玖  蒋雪茵  张志林  许少鸿
基金项目:国家自然科学基金资!59583004
摘    要:制备了可用于蓝色TFEL的粉末发光材料MGa2S4:Ce(M=Ca,Sr)并对其晶体结构进行了X射线分析,测量并研究了其激发光谱和发射光谱,研究了Ce3 浓度的变化对CaGa2S4:Ce和SrGa2S4:Ce的激发光谱.发射光谱、色纯度及发光强度的影响,同时研究了基质组份的改变对发光特性的影响.结果表明,CaGa2S4:Ce和SrGa2S4:Ce可发射纯蓝色光,色纯度好.对CaGa2S4:Ce来说,实现其高效率的、纯蓝色发射的最佳Ce3 浓度为6mol%,而SrGa2S4:Ce的最佳Ce3 浓度为3~4mol%.

关 键 词:CaGa2S4:Ce  SrGa2S4:Ce  光致发光  蓝色发光材料

Study for Photoluminescence Characteristics of the Blue-emiting Phosphor MGa_2S_4:Ce(M=Ca, Sr)
WANG Linjun, CHEN Zhongchuan, ZHAO WeimingTANG Chunjiu, JIANG Xueyin, ZHANG Zhilin, XU Shaohong. Study for Photoluminescence Characteristics of the Blue-emiting Phosphor MGa_2S_4:Ce(M=Ca, Sr)[J]. Journal of Inorganic Materials, 1997, 0(3)
Authors:WANG Linjun   CHEN Zhongchuan   ZHAO WeimingTANG Chunjiu   JIANG Xueyin   ZHANG Zhilin   XU Shaohong
Abstract:The blue-emitting phosphor MGa2S4:Ce(M=Ca, Sr) was prepared, and its crystallinity wasanalysed by X-ray diffraction. The excitation and emission spectra of MGa2S4:Ce were measuredand investigated, and the effects of the cerium concentration and the composition of host materialon the PL properties for MGa2S4:Ce powder were studied. The results of PL measurement showedthat MGa2S4:Ce phosphor achieved an even more saturated blue emission, and the optimumcerium concentration for high efficiency and more saturated blue emission was about 6mol% forMGa2S4:Ce, 3.0~4.0mol% for SrGa2S4:Ce.
Keywords:CaGa2S4:Ce   SrGa2S4:Ce   photoluminescence   blue-emitting phosphor
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