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Exoelectron emission and critical phenomena in CuCl crystals
Authors:N. A. Zakharov  T. V. Zakharova  V. A. Klyuev  V. V. Gorbachev
Affiliation:(1) Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia
Abstract:The temperature dependence of thermostimulated exoelectron emission (TSEE) and the specific heat c p of CuCl single crystals were studied in a broad temperature range. It is suggested that the TSEE peaks observed in the region of 375 and 420°C are due to the polytype formation and the structural transition from a sphalerite to wurtzite polymorph; the peak at 170°C is assigned to Cu2+ ions present in the CuCl crystals studied.
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