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Catalytic Activities of Alcohol Transformations Over 8-Ring Zeolites
Authors:Qingjun Zhu  Junko N. Kondo  Satoshi Inagaki  Takashi Tatsumi
Affiliation:(1) Chemical Resources Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta-cho, Midori-ku, 226-8503 Yokohama, Japan;(2) Division of Materials Science and Chemical Engineering, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, 240-8501 Yokohama, Japan
Abstract:Aluminosilicate H/CHA and H/MTF zeolites show remarkably different catalytic activities in the methanol and ethanol transformations although they have similar pore size of 8-membered ring structures. Moreover, the produced ethylene is further converted on H/CHA, but H/MTF is not active for the ethylene transformation. The correlations between the distinct catalytic differences and their intrinsic structural properties, including topology and acidity, are discussed.
Keywords:Methanol to olefin  Ethanol dehydration  Br?nsted acidity  8-Membered ring zeolite
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