Anion-directed self-assembly of metallosupramolecular coordination polymers of the radialene ligand hexa(2-pyridyl)[3]radialene |
| |
| Affiliation: | 1. Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi''an 710069, People''s Republic of China;2. College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022, People''s Republic of China;3. School of Material Science and Engineering, Beihang University, XueYuan Road No. 37, HaiDian District, Beijing 100191, People''s Republic of China |
| |
| Abstract: | Hexa(2-pyridyl)[3]radialene was prepared by reaction of di-2-pyridylmethane with tetrachlorocyclopropene. Reaction of this ligand with silver nitrate and silver hexafluorophosphate gave two different one-dimensional coordination polymers each with a 2:1 metal–ligand composition. X-ray crystal structures revealed that the structure and topology of the coordination polymer is strongly influenced by the anion. In the reaction with silver nitrate the ligand self-assembled to give a helical one-dimensional coordination polymer, but when silver hexafluorophosphate was used, a coordination polymer, composed of Ag3L2 prismate cages linked by linear-bridging silver atoms, was obtained. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
