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分级冷凝与电捕获器分离精制生物油研究
引用本文:石文,张长森,徐兴敏,任献涛,马梅英,张瑞芹.分级冷凝与电捕获器分离精制生物油研究[J].现代化工,2010,30(3).
作者姓名:石文  张长森  徐兴敏  任献涛  马梅英  张瑞芹
作者单位:郑州大学环境科学研究院及化学系,河南,郑州,450001;郑州大学化学系,河南,郑州,450001
基金项目:河南省科技厅资助项目 
摘    要:利用分级冷凝系统及电捕获器分离收集生物油,共得到5种生物油。研究了5种生物油的产率分布及其含水量、热值、黏度、pH等理化特性,分析了生物油的化学组成,考察了化合物在5种生物油中的分布,同时对分级冷凝系统及电捕获器分离生物油的效率作了统计评价。研究表明,电捕获器提高了生物油25.9%的产率,通过分级冷凝系统可以有效地分离脱除生物油中的水分。分级冷凝系统及电捕获器可以完全分离大分子量的酚类、醛酮类物质,但对乙酸等小分子量的物质分离效果不显著。

关 键 词:生物油  分级冷凝  电捕获器  精制

Separation and refinement of bio-oil by fractional condensation and electrostatic precipitator
SHI Wen,ZHANG Chang-sen,XU Xing-min,REN Xian-tao,MA Mei-ying,ZHANG Rui-qin.Separation and refinement of bio-oil by fractional condensation and electrostatic precipitator[J].Modern Chemical Industry,2010,30(3).
Authors:SHI Wen  ZHANG Chang-sen  XU Xing-min  REN Xian-tao  MA Mei-ying  ZHANG Rui-qin
Abstract:Five kinds of bio-oil are collected by fractional condensation and electrostatic precipitator.The yield distribution and physical-chemical properties of the bio-oil,such as water content,calorific value,viscosity,pH value,etc.,are studied.The chemical composition of bio-oils is analyzed,and the distribution in five kinds of bio-oil is investigated.The separating capability of fractional condensation and electrostatic precipitator is statistically evaluated.The results indicate that electrostatic precipitator can increase the yield of bio-oil by 25.9%,and the fractional condensation effectively separates water from the bio-oil.The results also show that the fractional condensation and electrostatic precipetator can completely separate large phenols,aldehydes and ketones,but they cannot separate acetic acid and other small compounds very well.
Keywords:GC-MS  bio-oil  fractional condensation  electrostatic precipetator  GC-MS  refinement
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