Initiation and early growth mechanisms of corrosion fatigue cracks in stainless steels

The mechanism of corrosion fatigue crack initiation in stainless steels was examined in both air and chloride solutions. For a tempered martensitic, a duplex and a soft martensitic steel it is shown that the decrease of the fatigue strength from the value measured in air to that measured in corrosive environments depends primarily upon the stability of the protective film. If the passivity is stable, cracks are found to originate almost exclusively at oxide inclusions. Cracking or debonding were found to occur. For the duplex steel in the vicinity of the inclusion there were pronounced emerging persistent slip bands. They cause localized corrosion attack, thus allowing cracks to be formed more easily. If pitting is superposed, crack nucleation always occurs at the base of the pit. Pit formation and growth rate are accelerated by cyclic loading.