The Spider DMA: A miniature radial differential mobility analyzer

Abstract

The Spider differential mobility analyzer (DMA) is a novel, miniaturized radial DMA developed to provide size classification in the 10–500?nm range for applications requiring high portability and time resolution. Its external dimensions are ～12?cm in diameter by 6?cm in height (excluding tubing); it weighs ～350?g, and is designed to operate at 0.6–1.5?L/min sheath and 0.3?L/min sample flowrates. It features a new sample inlet geometry that is designed to produce a uniform azimuthal particle distribution at the entrance of the classifier, optimized sample/sheath flow streams introduction in the classifier to minimize particle delays, and extension of the electric field interaction volume for ～30% enhanced dynamic range. Based on three-dimensional finite element simulations of flows, electric fields, and particle trajectories, we demonstrate that the Spider DMA transfer functions can be predicted with high fidelity using a parameterized fit based on the Stolzenburg semi-analytical model. Experimental characterization of the instrument response with size-selected particles confirmed close agreement with model prediction; mobility size response is linear over three orders of magnitude in mobility span. Electrical ground shielding of the external surfaces of the DMA has been found to be necessary to avoid particle losses associated with field effects as the high voltage operating limit is approached. The mean deviation between the reference size of polystyrene latex spheres and the Spider DMA measurement is less than 2%, corroborating its high sizing precision and potential for high quality size distribution measurements.

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