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碳化法制备超细球形碳酸钙初探
引用本文:向兰,向英,袁红霞,王亭杰.碳化法制备超细球形碳酸钙初探[J].过程工程学报,2002,2(1):50-54.
作者姓名:向兰  向英  袁红霞  王亭杰
作者单位:清华大学化工系,北京,100084
摘    要:研究了利用改进的碳化法合成超细球形碳酸钙的可行性. 考察了布气方式(板式及管式气体分布器)、化学添加剂以及CO2/N2混合气体组成对碳酸钙粒径和形貌的影响. 结果表明,采用小气泡及CO2含量较高的混合气体有利于形成超细碳酸钙,加入少量添加剂如ZnCl2,MgCl2或EDTA可明显改变碳酸钙粒子的形貌和大小.

关 键 词:碳酸钙  超细粉体  碳化法  管式分布器  添加剂
文章编号:1009-606X(2002)01-0050-05
修稿时间:2001年3月5日

Preparation of Super-fine Spherical CaCO3 by the Carbonation Method
XIANG Lan,XIANG Ying,YUAN Hong-xia,WANG Ting-jie.Preparation of Super-fine Spherical CaCO3 by the Carbonation Method[J].Chinese Journal of Process Engineering,2002,2(1):50-54.
Authors:XIANG Lan  XIANG Ying  YUAN Hong-xia  WANG Ting-jie
Abstract:The feasibility of preparing super-fine CaCO3 powder by an improved carbonation method was studied.The influence of gas distribution, chemical agents and CO2/N2 mixture on the size and morphology of CaCO3 was investigated. Bubbles with smaller size and gas mixture with higher CO2 concentration are favorable to the formation of super-fine CaCO3. The morphology and diameter of CaCO3 product are influenced obviously by the addition of additives such as ZnCl2, MgCl2 or EDTA .
Keywords:calcium carbonate  super-fine powder  carbonation method  tube sparger  additive
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