Abstract: | Effects of a maleated triblock copolymer of styrene–(ethylene‐co‐butene)–styrene (SEBS‐g‐MA) on compatibilization and mechanical properties of nylon‐12,12/nylon‐6 blends were investigated. The results showed that addition of SEBS‐g‐MA could improve the compatibility between nylon‐12,12 and nylon‐6. Nylon‐12,12 could disperse very well in nylon‐6 matrix, although the dispersion of nylon‐6 was poor when nylon‐6 was the dispersed phase. At a fixed nylon‐12,12/nylon‐6 ratio of 30/70, supertoughness was achieved with addition of 15% SEBS‐g‐MA in weight. Scanning electron microscopy of the impact‐fractured surface indicated that cavitation and matrix shear yielding were the predominant mechanisms of impact energy dissipation. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 93: 1446–1453, 2004 |