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侧链含PDMS的改性PUA复合乳液的制备与性能
引用本文:岳瑞峰,李树材.侧链含PDMS的改性PUA复合乳液的制备与性能[J].天津轻工业学院学报,2010(3):30-33.
作者姓名:岳瑞峰  李树材
作者单位:天津科技大学材料科学与化学工程学院,天津300457
摘    要:采用阴离子自乳化法合成了聚氨酯分子侧链上含聚二甲基硅氧烷(PDMS)的改性水性聚氨酯-丙烯酸酯系列复合乳液(SiPUA),主要探讨了氨乙基氨丙基聚二甲基硅氧烷(AEAPS)含量对SiPUA乳液及其涂膜性能的影响.结果表明,AEAPS在SiPUA中质量分数为6%时,乳液稳定性良好;涂膜的吸水率明显降低,断裂伸长率增加,但拉伸强度有所减小.

关 键 词:PUA  PDMS  改性  性能

Preparation and Performance of Modified PUA Composite Emulsion with PDMS Side Chain
YUE Rui-feng,LI Shu-cai.Preparation and Performance of Modified PUA Composite Emulsion with PDMS Side Chain[J].Journal of Tianjin University of Light Industry,2010(3):30-33.
Authors:YUE Rui-feng  LI Shu-cai
Affiliation:(College of Material Science and Chemical Engineering,Tianjin University of Science & Technology, Tianjin 300457 ,China)
Abstract:A series of modified waterborne polyurethane-acrylate hybrid emulsion (SiPUA) containing PDMS side chains in PU were synthesized using anionic self-emulsion method. The effect of aminoethylaminopropyl polydimethylsiloxane (AEAPS) content on properties of SiPUA emulsion and film from SiPUA emulsion were investigated chiefly. The results show that when AEAPS contents in the SiPUA reach to 6%,the SiPUA emulsion has good stability,water absorption ratio and tensile strength of the film decrease ,but elongation at break increases.
Keywords:PUA  PDMS  modified  performance
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