| 含二硫代甲酸酯配体铁硫簇合物的合成与表征 |
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| 引用本文： | 韩聪,刘雁红,黄骁南,刘伟.含二硫代甲酸酯配体铁硫簇合物的合成与表征[J].天津轻工业学院学报,2010(5):13-16. |
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| 作者姓名： | 韩聪 刘雁红 黄骁南 刘伟 |
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| 作者单位： | 天津科技大学理学院,天津300457 |
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| 基金项目： | 天津科技大学科学研究基金资助项目（20070209） |
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| 摘 要： | 报道通过2–呋喃甲硫醇/十二羰基三铁/三乙胺体系所形成的中间物（μ-2-SCH2C4H3O）（μ-CO）Fe2（CO）6]Et3NH同CS2作用生成络阴离子（μ-2-SCH2C4H3O）（μ-S C—S—）Fe2（CO）6]后,同卤代物原位反应,合成了3个新颖的含μ–二硫代甲酸酯配体的铁硫簇合物（μ-2-SCH2C4H3O）（μ-RS—C S）Fe2（CO）6（R=CH3、CH2Ph、CH2COOC2H5）.这3个新颖配合物均通过核磁共振氢谱、红外光谱和元素分析表征了其结构.
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| 关 键 词： | 铁硫簇合物 络阴离子[（μ-2-SCH2C4H3O）（μ-SC—S-）Fe2（CO）6] 2–呋喃甲硫醇 |
Synthesis and Characterization of Fe-S Cluster Complexes Containing Dithioformate Ligand |
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| HAN Cong,LIU Yan-hong,HUANG Xiao-nan,LIU Wei.Synthesis and Characterization of Fe-S Cluster Complexes Containing Dithioformate Ligand[J].Journal of Tianjin University of Light Industry,2010(5):13-16. |
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| Authors: | HAN Cong LIU Yan-hong HUANG Xiao-nan LIU Wei |
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| Affiliation: | (College of Science,Tianjin University of Science ＆ Technology,Tianjin 300457,China) |
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| Abstract: | Three new butterfly-shaped clusters containing dithiofromate ligand：（μ-2-SCH2C4H3O）（μ-RS—C S） Fe2（CO）6（R=CH3,CH2Ph,CH2COOC2H5）have been synthesized by the situ reaction of （μ-2-SCH2C4H3O）（μ-CO）Fe2（CO）6] Et3NH derived from the system of Fe3（CO）12,2-furyl methanethiol and triethylamine with CS2,followed by treatment of complex anion （μ-2-SCH2C4H3O）（μ-S C—S—）Fe2（CO）6] with organic halides.The structures of the three new compounds were fully characterized by elemental analysis,IR and 1H NMR spectroscopies. |
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| Keywords: | sulfur-iron clusters complex anion [（μ-2-SCH2C4H3O）（μ-S C—S-）Fe2（CO）6] 2-furylmethanethiol |
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