Electrochemical Behavior of Heteropoly Acid Anions Adsorbed in Electrodes Modified with Mesoporous Molecular Sieve Silica |
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Authors: | Wenjiang LI Zichen WANG Changqing SUN Muyu ZHAO Youwei YAO Aili CUI |
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Affiliation: | Department of Chemistry, Jilin University, Changchun 130023, China... |
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Abstract: | Heteropoly acid H4SiW12O48 (denoted as SiW12) was assembled with the mesoporous materials MCM-41 modified with 3-aminopropyltriethoxysilane (APTES) (denote MCM-41((m))). The electrochemical behavior of SiW12/MCM-41((m)) complexes-based electrode indicated SiW12 anion was adsorbed by MCM-41((m)). In MCM-41((m)) electrode, large voltammetric waves, showing that the electrostatic bound ions adsorbed in MCM-41((m)) were electrochemically active. The potential application as amperometric sensors for nitrite is anticipated. |
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