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新生态铁锰氧化物混凝除磷效果研究
引用本文:刘可,马军,关小红,秦庆东,余敏.新生态铁锰氧化物混凝除磷效果研究[J].中国给水排水,2009,25(21).
作者姓名:刘可  马军  关小红  秦庆东  余敏
作者单位:哈尔滨工业大学,城市水资源与水环境国家重点实验室,黑龙江,哈尔滨,150090
基金项目:教育部科技创新工程重大项目培育基金 
摘    要:采用FeSO_4和KMnO_4反应制备新生态铁锰氧化物除磷,比较了Fe_2(SO_4)_3和FeSO_4/KMnO_4两种混凝工艺的除磷效果,并考察了FeSO_4/KMnO_4除磷过程中的影响因素.结果表明,在相同条件下,FeSO_4/KMnO_4的除磷效果比Fe_2(SO_4)_3的要好,当铁盐投量(以Fe计)为5mg/L时,FeSO_4/KMnO_4和Fe_2(SO_4)_3对磷的去除率分别为90.2%和82.3%;KMnO_4与FeSO_4的最佳物质的量比为0.33;FeSO_4/KMnO_4的除磷效果随Fe~(2+)投量的增加而升高,随初始TP浓度和pH的增加而降低;当混凝时间由10 min增至60 min时,FeSO_4/KMnO_4对磷的去除率无明显变化.

关 键 词:新生态铁锰氧化物  高锰酸钾  硫酸亚铁  混凝  除磷

Study on Phosphorus Removal by Freshly Formed Fe/Mn Oxide Coagulation
LIU Ke,MA Jun,GUAN Xiao-hong,QIN Qing-dong,YU Min.Study on Phosphorus Removal by Freshly Formed Fe/Mn Oxide Coagulation[J].China Water & Wastewater,2009,25(21).
Authors:LIU Ke  MA Jun  GUAN Xiao-hong  QIN Qing-dong  YU Min
Affiliation:LIU Ke,MA Jun,GUAN Xiao-hong,QIN Qing-dong,YU Min(State Key Laboratory of Urban Water Resource and Environment,Harbin Institute of Technology,Harbin 150090,China)
Abstract:Freshly formed Fe/Mn oxide was prepared by FeSO4 and KMnO4 to remove phosphorus.The phosphorus removal efficiencies of Fe2(SO4)3 and FeSO4/KMnO4 coagulation processes were compared,and the factors affecting phosphorus removal by FeSO4/KMnO4 were investigated.The results show that the phosphorus removal efficiency of FeSO4/KMnO4 is better than that of Fe2(SO4)3 under the same conditions.When the dosage of Fe is 5 mg/L,the phosphorus removal rates of FeSO4/KMnO4 and Fe2(SO4)3 are 90.2% and 82.3% respectively....
Keywords:freshly formed Fe/Mn oxide  potassium permanganate  ferrous sulfate  coagulation  phosphorus removal
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