| 2, 4, 6-三硝基氯苯的表征及晶体结构 |
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| 引用本文： | 苗艳玲,张同来,乔小晶,张建国,于仁光,郁开北. 2, 4, 6-三硝基氯苯的表征及晶体结构[J]. 火炸药学报, 2003, 26(4): 37-40 |
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| 作者姓名： | 苗艳玲 张同来 乔小晶 张建国 于仁光 郁开北 |
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| 作者单位： | 1. 北京理工大学机电工程学院,北京,100081
2. 中科院成都有机所分析测试中心,四川,成都,640041 |
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| 摘 要： | 从丙酮溶液中培养了2,4,6-三硝基氯苯(TNCB)的单晶,通过元素分析、红外光谱分析和X-射线单晶衍射分析对TNCB进行了结构表征,属于单斜晶系,P2(1)/c空间群,a=1.2501(1)nm, b= 0.6803(1) nm, c=1.1038(1) nm, β= 102.842(9)°, V= 0.91526(15) nm3, Z=2, Dc = 1.797g/cm3, μ(MoKα)=0.438 /mm, F(000)=496, R1= 0.0395, ωR2= 0.0991.
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| 关 键 词： | 2，4，6-三硝基氯苯 表征 晶体结构 元素分析 红外光谱分析 X-射线单晶衍射分析 TNCB |
Characterization and Crystal Structure of 2, 4, 6-Trinitrochlorobenzene |
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| Abstract. Characterization and Crystal Structure of 2, 4, 6-Trinitrochlorobenzene[J]. Chinese Journal of Explosives & Propellants, 2003, 26(4): 37-40 |
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| Authors: | Abstract |
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| Abstract: | 2, 4, 6-Trinitrochlorobenzene(TNCB)single crystal was cultivated out from acetone solution, and characterized by X-ray diffraction analysis, element analysis and IR. It belongs to monoclinic space group P2(1)/c, with crystal parameters of a=1.2501(1) nm, b=0.6803(1) nm, c=1.1038 (1) nm, β=102.842(9)°, V=0.91526(15) nm3, Z=2, Dc=1.797 g/cm3, μ(MoKα)=0.438 /mm, F(000)=496, R1=0.039 5, ωR2=0.099 1. |
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| Keywords: | 2 4 6-Trinitrochlorobenzene crystal structure characterization |
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