| 微波辅助合成棕榈酸异辛酯 |
| |
| 引用本文： | 金丽,于东冬,赵晓丽,赵颖,刘岩,杨莹丽,范宏亮,周建光,金钦汉.微波辅助合成棕榈酸异辛酯[J].辽宁石油化工大学学报,2006,26(4):64-66. |
| |
| 作者姓名： | 金丽 于东冬 赵晓丽 赵颖 刘岩 杨莹丽 范宏亮 周建光 金钦汉 |
| |
| 作者单位： | 1. 吉林大学化学学院,吉林省光谱分析仪器工程技术研究中心,吉林,长春,130023
2. 解放军第二○八医院,吉林,长春,130062 |
| |
| 摘 要： | 在微波辐射条件下研究了棕榈酸异辛酯的合成。以棕榈酸,2-乙基己醇(异辛醇)为原料,以对甲基苯磺酸为催化剂,其最佳合成条件为:醇酸摩尔比为3∶2,反应温度为110℃,反应时间为30 min,催化剂的质量分数为0.17%(以原料总质量计质量分数),酯化率可达99%。与常规加热方法相比,具有反应温度低,时间短,能耗低等优点。
|
| 关 键 词： | 棕榈酸异辛酯 微波 合成 |
| 文章编号： | 1672-6952（2006）04-0064-03 |
| 收稿时间： | 2006-09-22 |
| 修稿时间： | 2006-09-26 |
Synthesis of 2- Ethylhexyl Palmitate Under Microwave Irradiation |
| |
| JIN Li,YU Dong-dong,ZHAO Xiao-li,ZHAO Ying,LIU Yan,YANG Ying-li,FAN Hong-liang,ZHOU Jian-guang,JIN Qin-han.Synthesis of 2- Ethylhexyl Palmitate Under Microwave Irradiation[J].Journal of Liaoning University of Petroleum & Chemical Technology,2006,26(4):64-66. |
| |
| Authors: | JIN Li YU Dong-dong ZHAO Xiao-li ZHAO Ying LIU Yan YANG Ying-li FAN Hong-liang ZHOU Jian-guang JIN Qin-han |
| |
| Abstract: | 2-Ethylhexyl palmitate was synthesized by microwave irradiation with palmitic acid,isooctanol as raw material and p-toluenesulfonic acid as catalyst.The yield is 99% when the molar ratio of alcohol to acid is 3∶2,reaction temperature is 110 ℃,reaction time is 30 minutes,mass fraction of catalyst is 0.17%(based on total mass of reactants) and water-carrying reagent is added.By contrast with the conventional heating method,this method is better with short reaction time,convenient operation and high yield. |
| |
| Keywords: | 2 Ethylhexyl palmitate Microwave Synthesis |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
