Effect of Y2O3 on cracking susceptibility of laser-clad Ti-based composites coatings

Ti-based composite coatings reinforced by in situ synthesized TiB and TiC were deposited on Ti₆Al₄V substrates by laser cladding. The effects of Y₂O₃ on the microstructure and cracking susceptibility of the coatings were investigated in details. It is shown that a small amount of Y₂O₃ addition can significantly refine the microstructure of the coatings by hastening spheroidization of the primary phase structure. The maximum refinement in microstructure was obtained with the optimum (2 wt%) addition of Y₂O₃. Moreover, it can increase the volume fraction of TiC and reduce the residual stress of the coatings due to the decrease in lattice distortion of the α(Ti) matrix. All of these factors lead to the reduction in cracking susceptibility of the coatings containing Y₂O₃ on the premise that the hardness of the coatings is improved. The fracture toughness of the coatings without and with Y₂O₃ (2 wt%) is 8.32 and 17.36 MPa·m^1/2, respectively. Scanning electron microscope examination reveals a transition of the fractured surfaces from cleavage fracture to quasi-cleavage fracture resulting from the Y₂O₃ addition.