Quantification of deep hole-trap filling by molecular p-doping: Dependence on the host material purity |
| |
Authors: | Max L Tietze Karl Leo Björn Lüssem |
| |
Affiliation: | Institut für Angewandte Photophysik (IAPP), Technische Universität Dresden, George-Bähr-Straße 1, 01069 Dresden, Germany |
| |
Abstract: | The p-doping effect of the fluorinated fullerene C60 F36 doped into organic thin films of N,N,N′,N′-tetrakis(4-methoxyphenyl)-benzidine (MeO-TPD) of different purification grades is systematically investigated by photoemission spectroscopy. By reducing the molar doping ratio to MR = 2.9 × 10?4, the Fermi-level shift upon doping is resolved in particular at very low doping concentrations. In comparison to four times sublimated MeO-TPD, 5 times more C60F36 molecules have to be doped into unpurified MeO-TPD films to shift the Fermi-level just above its intrinsic position. This finding is discussed in terms of a statistical model, showing that narrow deep hole-trap states are additionally present in the unpurified host material which are hindering an efficient generation of free charge carriers at molar doping ratios below MR = 0.002. |
| |
Keywords: | Molecular p-doping Organic semiconductors Fermi-level Deep trap-states Ultra-violet photoemission spectroscopy |
本文献已被 ScienceDirect 等数据库收录! |
|