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用改进矩阵计算法同时分光光度测定铝和铁
引用本文:张大伦. 用改进矩阵计算法同时分光光度测定铝和铁[J]. 武汉化工学院学报, 1993, 0(2)
作者姓名:张大伦
作者单位:武汉化工学院精细化工系
摘    要:采用改进矩阵计算法,研究微量Al,Fe混和试样的同时分光光度测定。讨论了计算原理,确定了Al-CAS-CTMAB及Fe-CAS-CTMAB显色反应的最佳条件,提出了根据试样组分数,确定所选测定波长数及配制混合标样数的原则,并选择了最佳波长,对六个含1-5μg/25mL Al+Fe混合试样,进行了42次测定,相对误差和相对标准偏差一般在1-5%,结果满意。

关 键 词:改进矩阵计算法  多组分同时测定  分光光度法  铝和铁

Simultaneous Determination of Al and Fe by Spectrophotometry with the Aid of A Modified Matrix Algorithm
Zhang Dalun. Simultaneous Determination of Al and Fe by Spectrophotometry with the Aid of A Modified Matrix Algorithm[J]. Journal of Wuhan Institute of Chemical Technology, 1993, 0(2)
Authors:Zhang Dalun
Affiliation:Zhang Dalun
Abstract:Simultaneous determination of multi-xomponent by Cpectrophotometry is stu-died with the did of a modified matrix algorithm. The optimal conditions for the chromo-reaction of Al-CAS-CTMAB and Fe-CAS-CTMAB are detemined. 42 deter-minations are made for six samples containing 1~ 5 tig/ 25mL of Al+Fe, and the results are satisfactory with the relative standard deviations of 1 ~ 5%.
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