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Influence of chain-transfer reactions on the molecular-weight-distribution function of diene rubber on a neodymium-containing catalyst system
Authors:G A Aminova  G V Manuiko  V V Bronskaya  T V Ignashina  G S D’yakonov  D V Bashkirov  É V Demidova
Affiliation:(1) Kazan’ State Technological University, 68 K. Marks Str., Kazan’, 420015, Russia
Abstract:The numerical solution of a system of differential equations for the concentrations of the reaction system’s macromolecules, which describe the synthesis of diene rubber on a neodymium-containing catalyst system, has been obtained. The influence of the chain-transfer reactions on the number distributions of the monomer links of macromolecules with an assigned number of active sites has theoretically been investigated. Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 81, No. 6, pp. 1203–1207, November–December, 2008.
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