| 离子液体在Suzuki偶联反应中的应用 |
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| 引用本文： | 李鹏宇,李猛,白雪峰. 离子液体在Suzuki偶联反应中的应用[J]. 化学与粘合, 2013, 0(6): 53-57 |
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| 作者姓名： | 李鹏宇 李猛 白雪峰 |
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| 作者单位： | [1]黑龙江省科学院石油化学研究院,黑龙江哈尔滨150040 [2]黑龙江大学化学化工与材料学院,黑龙江哈尔滨150080 |
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| 基金项目： | 黑龙江省科学院科研基金项目 |
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| 摘 要： | 过渡金属Pd催化的Suzuki偶联反应是构建C-C键的重要反应之一,在许多领域都有着广泛应用.在离子液体中进行的Suzuki偶联反应具有反应活性高、选择性好等特点.含有Pd配体的功能化离子液体直接催化Suzuki偶联反应可提高催化活性,容易实现产物与催化剂分离.固载化离子液体可有效地解决催化剂难以重复使用的问题.
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| 关 键 词： | Suzuki反应 Pd配体 离子液体 功能化 |
Application of Ionic Liquids in Suzuki Coupling Reaction |
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| LI Peng-yu,LI Meng,BAI Xue-feng. Application of Ionic Liquids in Suzuki Coupling Reaction[J]. Chemistry and Adhesion, 2013, 0(6): 53-57 |
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| Authors: | LI Peng-yu LI Meng BAI Xue-feng |
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| Affiliation: | 1.College of Chemistry and Material Science, Heilongjiang University, Harbin 150080, China; 2.Institute of Petrochemistry, Heilongjiang Academy of Sciences, Harbin 150040, China; 3.Institute of Petrochemistry, Heilongjiang Academy of Sciences, Harbin 150040, China; College of Chemistry and Material Science, Heilongjiang University, Harbin 150080, China;) |
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| Abstract: | The Suzuki coupling reaction catalyzed by transition metal Pd is one of the most important C-C coupling reactions,which has been widely used in many fields.Suzuki coupling reactions in ionic liquids represent the characteristics of high reactivity and good selectivity.The functionalized ionic liquids with Pd ligand group can improve catalytic activity and easily realize the separation between product and catalyst.The supported ionic liquids can effectively solve the problem of catalyst reuse. |
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| Keywords: | Suzuki coupling reactions palladium ligands ionic liquids functionalized |
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