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聚天冬氨酸阻垢机理研究
引用本文:王剑波,;卢园,;曹怀宝.聚天冬氨酸阻垢机理研究[J].淮南工业学院学报,2009(1):23-26.
作者姓名:王剑波  ;卢园  ;曹怀宝
作者单位:[1]安徽理工大学学化学工程学院,安徽淮南232001; [2]常州纺织服装职业技术学院纺化系,江苏常州213000
摘    要:以L-天冬氨酸为原料,H3PO4为催化剂,碳酸丙烯酯为溶剂,微波辐射合成了聚天冬氨酸。静态阻垢法测定PASP具有优良的阻垢性能。运用SEM、IR和XRD对PASP阻碳酸钙垢的结构进行分析。结果表明:加入PASP后,碳酸钙垢形成了新的晶型球霰石,从而起到阻垢作用。

关 键 词:阻垢剂  聚天冬氨酸  阻垢机理  碳酸钙垢

Study on Antiscaling Mechanism of Polyaspartic Acid
Affiliation:WANG Jian-bo,LU Yuan,CAO Huai-bao(1.Department of Chemical Engineering,Anhui University of Science and Teehnology,Huainan Anhui 232001,China; 2. Department of Textile Chemistry Engineering, Changzhou Textile Garment Institute, Changzhou Jiangsu 213000, China)
Abstract:Polyaspartic acid was synthesized by L-aspartic acid as raw material, with H3PO4 as catalyst in medium of propylene carbonate under microwave radition. Its performance of scale inhibition was examined by static scale inhibition testing method, and the results showed that polyaspartic acid is a excellent scale-inhibitor. The structure of calcium carbonate scale inhibited by PASP was investigated by SEM, FTIR and XRD. The results showed that at presence of PASP, vaterite polymorphs occur in scale, which plays the role of scale-inhibition.
Keywords:scale inhibitors  polyaspartic acid  antiscaling mechanism  calcium carbonate scale
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