Photo‐oxidation of polymers: Validation of oxygen uptake and relationship with extent of hydroperoxidation

In this piece of work we focused our attention on the peroxidation step and alongside considered hydroperoxides as probes for the overall oxidative process. This technique of oxygen uptake actually monitors the amount of oxygen consumed during polymer degradation. Our present work aimed to investigate this technique to evaluate the oxygen uptake during in situ photoirradiation, under controlled atmosphere. Our experimental results clearly elucidate that the oxygen consumption data accounts for a very early stage of aging during the photo‐oxidation of polymers and provides us with an accurate and sensitive diagnosis about the formation of hydroperoxides. A straight‐line relationship was exhibited under our experimental conditions while observing a relation between oxygen pressure drop and hydroperoxide content in the polymer. This correlation was dependent upon the nature of polymer and of course on the aging conditions (temperature, irradiation, oxidative atmosphere). The impact of environmental atmosphere on aging was particularly kept in mind. To conclude, we emphasized that oxygen uptake is a promisingly powerful tool to identify the impact of the overall environmental parameters on the polymer photoaging. An important implication was on the understanding of atmospheric factors (including pollutants such as O₃, NO_x, etc.), which is usually given minor importance, on the degradation of polymer upon outdoor weathering. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci, 2006