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Kinetic study on the UV‐induced photopolymerization of epoxy acrylate/TiO2 nanocomposites by FTIR spectroscopy
Authors:Fusheng Li  Shuxue Zhou  Bo You  Limin Wu
Abstract:The kinetics of the photopolymerization of epoxy acrylate/TiO2 nanocomposites, with 2′2‐dimethoxy‐1,2‐diphenylethan‐1‐one (Irgacure 651) or benzophenone/N‐methyl diethanolamine as photoinitiators, were studied by FTIR spectroscopy. It was found that nanocomposites had a decreasing photopolymerization rates in comparison with pure epoxy acrylate. The photopolymerization rate of the nanocomposite could also be influenced by initiator types, oxygen, film thickness, irradiation intensity, dispersing media of TiO2 slurry, and so forth. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 99: 3281–3287, 2006
Keywords:TiO2  nanocomposite coatings  photopolymerization kinetics  UV curing
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