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Irradiation Grafted Polymeric Films. II. Gas Transport Properties of Hydrated Potassium Acrylate-Grafted Polyethylene Films
Abstract:Abstract

The permeability constants of oxygen and carbon dioxide through hydrated potassium acrylate-grafted polyethylene films increase rapidly as the degree of hydration of the films increases above about 28 wt %. Below about 28 wt %, the carbon dioxide permeability constant increases with the degree of hydration. In the case of oxygen, the opposite is true.

The separation factor (CO2/O2) increases rapidly with film hydration up to about 28 wt %. Above this degree of hydration, the separation factor gradually approaches the value for pure water. An explanation for the results obtained is presented.
Keywords:Pervaporation  Sulfonation  Chemical grafting  Glycidyl methacrylate  Poly(4-methyl-l-pentene)
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