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THE CONFORMATIONAL MECHANISM OF THERMOELASTICITY OF ORIENTED POLYETHYLENE
Abstract:Temperature variations of oriented polyethylene (PE) with a draw ratio of ~ 450% were measured in longitudinal adiabatic tension and compression (along the orientation axis) and transverse compression. Stress-strain curves (for tension and compression) were recorded. Linear thermal expansion coefficients in the longitudinal and transverse direction were measured. Thermoelastic characteristics and also thermal properties of oriented PE were quantitatively analyzed. It has been concluded that conformational dynamics has a dominating influence on these characteristics.
Keywords:polyethylene  thermoelasticity  tension and compression  temperature  isomeric transitions  conformational dynamics
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