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Poly(vinyl alcohol) Based pH Responsive Semi-IPN Hydrogels: A Comparative Swelling Investigation
Abstract:The semi-interpenetrating polymer network (IPN) hydrogels composed of poly(vinyl alcohol) (PVA) and random copolymers of poly(acrylamide-co-sodium methacrylate), poly(AAm-co-NMA); poly(acrylamide-co-potassium methacrylate), poly(AAm-co-KMA); poly(acrylamide-co-maleic acid), poly(AAm-co-MA) were prepared by conventional co-polymerization employing ammonium persulphate (APS)/N,N,N1,N1-tetraethylmethylenediamine (TMEDA) as redox initiating system in presence of N,N1-methylenebisacrylamide (MBA) as a crosslinker. The swelling behavior of these semi-IPN hydrogels were compared in detail in various swelling media, including different pH, salt, and biological fluids.
Keywords:diffusion coefficient  hydrogel  poly(vinyl alcohol) swelling behavior  semi-interpenetrating polymer network
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