| 高分子担载谷氨酸希夫碱铜配合物催化氧化环己烯研究 |
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| 引用本文： | 郝成君,王勇. 高分子担载谷氨酸希夫碱铜配合物催化氧化环己烯研究[J]. 化工时刊, 2009, 23(11): 48-50. DOI: 10.3969/j.issn.1002-154X.2009.11.014 |
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| 作者姓名： | 郝成君 王勇 |
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| 作者单位： | 平顶山学院化学化工学院,河南,平顶山,467002;河南工业职业技术学院化工系,河南,南阳,473009 |
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| 基金项目： | 河南省高等学校青年骨干教师资助计划项目(2004-194);;平顶山市科技攻关项目(2006061-1);;平顶山学院应用化学重点学科;;平顶山学院高层次人才科研启动经费资助项目 |
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| 摘 要： | 研究了高分子担载水杨醛谷氨酸希夫碱配合物（PS-Sal-Glu-M）催化氧化环己烯的性能，详细探讨了反应温度、反应时间、催化剂用量、反应添加剂对高分子担载水杨醛谷氨酸希夫碱铜配合物催化氧化环已烯的反应性能的影响。研究表明，在常压下，用分子氧作作为氧化剂，不需要溶剂及共还原剂，环己烯可以被氧化生成环己烯醇和环已烯酮，产物的分离提纯比较容易，催化剂可以循环使用。
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| 关 键 词： | 高分子担载谷氨酸希夫碱铜配合物 环己烯 催化氧化 分子氧 |
Polymer Bound Glutamic Acid Salicylaldehyde Schiff-base Complex Catalysts for Catalytic Oxidation of Cyclohexene with Molecular Oxygen |
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| Hao Chengjun Wang Yong. Polymer Bound Glutamic Acid Salicylaldehyde Schiff-base Complex Catalysts for Catalytic Oxidation of Cyclohexene with Molecular Oxygen[J]. Chemical Industry Times, 2009, 23(11): 48-50. DOI: 10.3969/j.issn.1002-154X.2009.11.014 |
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| Authors: | Hao Chengjun Wang Yong |
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| Affiliation: | Department of Chemistry and Chemical Engineering;Pingdingshan University;Henan Pingdingshan 467002;Department of Chemical Engineering;Henan Polytechnic Institute;Henan Nanyang 473009 |
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| Abstract: | The catalytic oxidation for cyclohexene with polymer bound L-Glutamic acid salicylaldehyde schiff-base complexes(PS-SalGlu-M) was investigated,a detailed study on the oxidation of cyclohexene with PS-SalGlu-Cu was made,such as reaction temperature,reaction time,catalyst use level,and additives,the reusability of PS-Sal-Glu-Cu on catalytic oxidation for cyclohexene had been studied.It is shown that cyclohexene could be directly oxidized by oxygen when catalyzed by PS-Sal-Glu-Cu without solvent and reductants... |
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| Keywords: | polymer bound glutamic acid salicylaldehyde schiff-base copper complex cyclohexene catalytic oxidation molecular oxygen |
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