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GO/Fe_3O_4/ZnO的制备及其光助Fenton降解苯酚
引用本文:李成希,吴坤坤,孟祖超,刘祥,李谦定,宋久旭.GO/Fe_3O_4/ZnO的制备及其光助Fenton降解苯酚[J].工业水处理,2017,37(2).
作者姓名:李成希  吴坤坤  孟祖超  刘祥  李谦定  宋久旭
作者单位:1. 西安石油大学化学化工学院,陕西西安,710065;2. 西安石油大学电子工程学院,陕西西安,710065
基金项目:陕西省自然科学基金项目(2013JQ2015);陕西省教育厅基金项目(2013JK0673);国家级大学生创新创业训练计划资助项目(201210705041);西安石油大学博士科研启动基金资助项目
摘    要:采用水热法制备了GO/Fe_3O_4/ZnO复合材料,并用SEM、FT-IR、XRD等手段对其进行了表征。以苯酚为降解目标,探讨了GO/Fe_3O_4/ZnO复合材料用量、H_2O_2投加量、苯酚浓度和pH等因素对降解苯酚效果的影响。实验结果表明,在GO/Fe_3O_4/ZnO投加量为200 mg/L,H_2O_2投加量为12 mmol/L,pH=7.2的条件下,利用该复合材料对苯酚质量浓度为88.85 mg/L的油田污水进行光催化Fenton降解,60 min后,苯酚降解率可达98%。

关 键 词:石墨烯  光催化  Fenton体系  可见光

Preparation of GO/Fe3O4/ZnO composite and its photo-assisted Fenton degradation of phenol
Li Chengxi,Wu Kunkun,Meng Zuchao,Liu Xiang,Li Qianding,Song Jiuxu.Preparation of GO/Fe3O4/ZnO composite and its photo-assisted Fenton degradation of phenol[J].Industrial Water Treatment,2017,37(2).
Authors:Li Chengxi  Wu Kunkun  Meng Zuchao  Liu Xiang  Li Qianding  Song Jiuxu
Abstract:The composite material GO/Fe3O4/ZnO has been prepared by hydrothermal method,and characterized by SEM,XRD and FT-IR. Having phenol as the degradation target,the influences of the factors,such as the dosages of the composite material GO/Fe3O4/ZnO,and H2O2,the concentration of phenol,the pH,etc. on the degradation effect of phenol are discussed. The experimental results show that using the composite materials ,under the following conditions:the GO/Fe3O4/ZnO dosage is 200 mg/L,H2O2 dosage 12 mmol/L,and pH=7.2,88.85 mg/L of oilfield wastewater is treated by the photo?catalysis Fenton degradation process. 60 min later,the phenol degradation rate can reach 98%.
Keywords:graphene  photo-catalysis  Fenton system  visible light
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